Professor James Crowley, Our people, Department of Chemistry

PhD(Chicago) MSc(Well)

Tel +64 3 479 7731
Location Science II, 2n10
Email jcrowley@chemistry.otago.ac.nz

For more information about the Crowley Research Group: http://blogs.otago.ac.nz/jamescrowley

Employment History and Qualifications

Professor, University of Otago 2015–
Senior Lecturer, University of Otago 2011-2015
Lecturer, University of Otago 2008–2011
British Ramsay Memorial Postdoctoral Fellow (with Prof. D. A. Leigh, FRS), University of Edinburgh 2006–2007
Postdoctoral Fellow (with Prof. D. A. Leigh, FRS), University of Edinburgh 2005–2006
S.M and Ph.D, The University of Chicago (Prof. B Bosnich, FRS) 2000-2005
B.Sc. (Hons) and M.Sc., Victoria University of Wellington (Dr. D. C. Weatherburn) 1994-1999

Awards and Distinctions

University of Otago, Division of Sciences Research Group of the Year 2016
Royal Australian Chemical Institute (RACI), Organometallic Chemistry Award 2015
Finalist in OUSA Supervisor of the Year Awards 2015
Chemical Society of Japan (CSJ) Asian International Distinguished Lectureship Award 2015
Royal Australian Chemical Institute (RACI), Alan Sargeson Lectureship 2014
Royal Society of Chemistry/New Zealand Institute of Chemistry Easterfield Award 2013
University of Otago Early Career Award for Distinction in Research 2011
British Ramsay Memorial Fellowship (U of Ed.) 2006-2008
Joan Shiu Award for Student Service, (U of C) 2004
Curtis-Gordon Scholarship for Chemistry (VUW) 1998

Relevant Disciplines

Organic / Inorganic / Organometallic / Materials / Supramolecular Chemistry / Nanoscience

My research interests are in synthetic organic, inorganic, organometallic and supramolecular chemistry. I am interested in the design and synthesis of new functional materials. I have expertise in a wide range of synthetic and spectroscopic techniques including NMR, IR, UV-vis and X-ray crystallography. Major areas of interest include:

CuAAC “Click” coordination chemistry. The mild and modular Cu(I)-catalyzed 1,3-cycloaddition of terminal alkynes with organic azides (the CuAAC “click” reaction) allows the ready formation of functionalised 1,4-disubstituted-1,2,3-triazole scaffolds and this has led to an explosion of interest in the coordination chemistry of these heterocycles. A diverse array of mono-, bi-, tri- and polydentate ligands incorporating 1,4-disubstituted-1,2,3-triazole units have been synthesised and characterised. Easy access to readily functionalised ligand architectures is of crucial importance in a range of different areas and we are exploiting these ligands for the development of new catalysts, metallo-pharmaceuticals, bio-imaging agents, metallosupramolecular architectures, and molecular machines.

Synthetic molecular machines (nanotechnology). It is well established that the fundamental processes of life at the cellular level are governed by complex biological molecular machines which convert chemical energy into work. My research group is interested in exploiting a range of interlocked and non-interlocked molecular architectures for the development of synthetic molecular machines. These efforts are motivated by the goal of creating synthetic devices or materials that, like their far more complex biological counterparts, could carry out tasks by exploiting controlled molecular-level mechanical motion; a key requirement for the development of useable nanotechnology.

Functional metallosupramolecular architectures. I am also interested in the engineering of functional molecular architectures via self-assembly. In particular we are attempting to exploit these self-assembled cages as novel metallo-pharmaceuticals, for drug delivery and as nanoreactors for carrying out chemical transformations.

Publications

Gearing, H. B., Söhnel, T., Young, P., Lisboa, L., Wright, L. J., Crowley, J. D., & Hartinger, C. G. (2024). Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures. Chemical Communications. Advance online publication. doi: 10.1039/D4CC03613A Journal - Research Article

Tremlett, W. D. J., Crowley, J. D., Wright, L. J., & Hartinger, C. G. (2024). Towards building blocks for metallosupramolecular structures: Non-symmetrically-functionalised ferrocenyl compounds. Dalton Transactions. Advance online publication. doi: 10.1039/d4dt01646g Journal - Research Article

Eastham, K., Kennedy, A. D. W., Scottwell, S. Ø., Bramham, J. E., Hardman, S., Golovanov, A. P., … Crowley, J. D., & Elliott, P. I. P. (2024). Photochemistry of Ru(II) triazole complexes with 6-membered chelate ligands: Detection and reactivity of ligand-loss intermediates. Inorganic Chemistry, 63, 9084-9097. doi: 10.1021/acs.inorgchem.4c00251 Journal - Research Article

Malina, J., Crowley, J. D., & Brabec, V. (2024). Interaction of dinuclear Co(III) cylinders with higher-order DNA structures. Chemico-Biological Interactions, 395, 111031. doi: 10.1016/j.cbi.2024.111031 Journal - Research Article

van Hilst, Q. V. C., Pearcy, A. C., Preston, D., Wright, L. J., Hartinger, C. G., Brooks, H. J. L., & Crowley, J. D. (2024). A dynamic covalent approach to [Pt_nL_2n]²ⁿ⁺ cages. Chemical Communications. Advance online publication. doi: 10.1039/D4CC00323C Journal - Research Article

2024

Journal - Research Article

Shillito, G. E., Preston, D., Crowley, J. D., Wagner, P., Harris, S. J., Gordon, K. C., & Kupfer, S. (2024). Controlling excited state localization in bichromophoric photosensitizers via the bridging group. Inorganic Chemistry. Advance online publication. doi: 10.1021/acs.inorgchem.3c04110

Journal - Research Other

Faulkner, L. A. V., & Crowley, J. D. (2024). The beauty of low symmetry: Non-statistical assembly of [Pd₂(L_A)(L_B)(L_C)(L_D)]⁴⁺ cages [Preview]. Chem, 10(2), 440-442. doi: 10.1016/j.chempr.2024.01.015

2023

Journal - Research Article

Pearcy, A. C., Lisboa, L. S., Preston, D., Page, N. B., Lawrence, T., Wright, L. J., … Crowley, J. D. (2023). Exploiting reduced-symmetry ligands with pyridyl and imidazole donors to construct a second-generation stimuli-responsive heterobimetallic [PdPtL₄]⁴⁺ cage. Chemical Science, 14, 8615-8623. doi: 10.1039/d3sc01354e

Tremlett, W. D. J., Söhnel, T., Crowley, J. D., Wright, L. J., & Hartinger, C. G. (2023). Ferrocene-derived palladium(II)-based metallosupramolecular structures: Synthesis, guest interaction, and stimulus-responsiveness studies. Inorganic Chemistry. Advance online publication. doi: 10.1021/acs.inorgchem.2c04399

Vasdev, R. A. S., Preston, D., Casey-Stevens, C. A., Martí-Centelles, V., Lusby, P. J., Garden, A. L., & Crowley, J. D. (2023). Exploiting supramolecular interactions to control isomer distributions in reduced-symmetry [Pd₂L₄]⁴⁺ cages. Inorganic Chemistry, 62, 1833-1844. doi: 10.1021/acs.inorgchem.2c00937

Journal - Research Other

Moree, L. K., Faulkner, L. A. V., & Crowley, J. D. (2023). Heterometallic cages: Synthesis and applications. Chemical Society Reviews. Advance online publication. doi: 10.1039/d3cs00690e

Pearcy, A. C., & Crowley, J. D. (2023). The biologically inspired abilities of metallosupramolecular architectures. Chemistry: A European Journal, 29, e.202203752. doi: 10.1002/chem.202203752

2022

Journal - Research Article

Lisboa, L. S., Riisom, M., Dunne, H. J., Preston, D., Jamieson, S. M. F., Wright, L. J., … Crowley, J. D. (2022). Hydrazone- and imine-containing [PdPtL₄]⁴⁺ cages: A comparative study of the stability and host-guest chemistry. Dalton Transactions, 51, 18438-18445. doi: 10.1039/d2dt02720h

Lisboa, L. S., Preston, D., McAdam, C. J., Wright, L. J., Hartinger, C. G., & Crowley, J. D. (2022). Heterotrimetallic double cavity cages: Syntheses and selective guest binding. Angewandte Chemie International Edition, 61, e202201700. doi: 10.1002/anie.202201700

Crowley, J. D., Findlay, J. A., & Ross, D. A. W. (2022). Ferrocene rotary switches featuring 2-pyridyl-1,2,3-triazole “click” chelates. European Journal of Inorganic Chemistry, 5, e202100948. doi: 10.1002/ejic.202100948

2021

Chapter in Book - Research

Crowley, J. D., Lisboa, L. S., & van Hilst, Q. V. C. (2021). Supramolecular systems: Metallo-molecular machines and stimuli responsive metallo-macrocycles and cages. In Reference module in chemistry, molecular sciences and chemical engineering. Elsevier. doi: 10.1016/B978-0-08-102688-5.00042-8

Journal - Research Article

Green, L. P. M., Steel, T. R., Riisom, M., Hanif, M., Söhnel, T., Jamieson, S. M. F., … Crowley, J. D., & Hartinger, C. G. (2021). Synthetic strategy towards heterodimetallic half-sandwich complexes based on a symmetric ditopic ligand. Frontiers in Chemistry, 9, 786367. doi: 10.3389/fchem.2021.786367

Ross, D. A. W., Findlay, J. A., Vasdev, R. A. S., & Crowley, J. D. (2021). Can 2-Pyridyl-1,2,3-triazole “click” ligands be used to develop Cu(I)/Cu(II) molecular switches? ACS Omega, 6, 30115-30129. doi: 10.1021/acsomega.1c04977

Ross, D. A. W., Mapley, J. I., Cording, A. P., Vasdev, R. A. S., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2021). 6,6'-ditriphenylamine-2,2'-bipyridine: Coordination chemistry and electrochemical and photophysical properties. Inorganic Chemistry, 60, 11852-11865. doi: 10.1021/acs.inorgchem.1c01435

Lisboa, L. S., Riisom, M., Vasdev, R. A. S., Jamieson, S. M. F., Wright, L. J., Hartinger, C. G., & Crowley, J. D. (2021). Cavity-containing [Fe₂L₃]⁴⁺ helicates: An examination of host-guest chemistry and cytotoxicity. Frontiers in Chemistry, 9, 697684. doi: 10.3389/fchem.2021.697684

Sutton, J. J., Preston, D., Traber, P., Steinmetzer, J., Wu, X., Kayal, S., … Crowley, J. D., … Gordon, K. C. (2021). Excited-state switching in Rhenium(I) bipyridyl complexes with donor–donor and donor–acceptor substituents. Journal of the American Chemical Society, 143, 9082-9093. doi: 10.1021/jacs.1c02755

Steel, T. R., Tong, K. K. H., Söhnel, T., Jamieson, S. M. F., Wright, L. J., Crowley, J. D., … Hartinger, C. G. (2021). Homodinuclear organometallics of ditopic N,N-chelates: Synthesis, reactivity and in vitro anticancer activity. Inorganica Chimica Acta, 518, 120220. doi: 10.1016/j.ica.2020.120220

Journal - Research Other

Vasdev, R. A. S., Findlay, J. A., Turner, D. R., & Crowley, J. D. (2021). Self-assembly of a redox active, metallosupramolecular [Pd₃L₆]⁶⁺ complex using a rotationally flexible ferrocene ligand. Chemistry: An Asian Journal, 16, 39-43. doi: 10.1002/asia.202001277

2020

Journal - Research Article

McNeill, S., Giles, N. M., Preston, D., Jones, P. P., Crowley, J. D., & Giles, G. I. (2020). The quadruply stranded metallo-supramolecular helicate [Pd₂ (hextrz)₄]⁴⁺ acts as a molecular mimic of cytolytic peptides. Chemical Research in Toxicology, 33, 1822-1834. doi: 10.1021/acs.chemrestox.0c00061

Shillito, G. E., Preston, D., Traber, P., Steinmetzer, J., McAdam, C. J., Crowley, J. D., … Gordon, K. C. (2020). Excited-state switching frustrates the tuning of properties in triphenylamine-donor-ligand rhenium(I) and platinum(II) complexes. Inorganic Chemistry, 59, 6736-6746. doi: 10.1021/acs.inorgchem.9b03691

Crlikova, H., Malina, J., Novohradsky, V., Kostrhunova, H., Vasdev, R. A. S., Crowley, J. D., … Brabec, V. (2020). Antiproliferative activity and associated DNA interactions of [Co₂L₃]⁶⁺ cylinders derived from bis(bidentate) 2-pyridyl-1,2,3-triazole ligands. Organometallics, 39, 1448-1455. doi: 10.1021/acs.organomet.0c00146

Lagesse, N. R., Tan, K. Y. L., Crowley, J. D., & Findlay, J. A. (2020). Planar 2-pyridyl-1,2,3-triazole derived metallo-ligands: Self-assembly with PdCl₂ and photocatalysis. Chemistry: An Asian Journal, 15, 1567-1573. doi: 10.1002/asia.202000284

Lisboa, L. S., Findlay, J. A., Wright, L. J., Hartinger, C. G., & Crowley, J. D. (2020). A reduced-symmetry heterobimetallic [PdPtL₄]⁴⁺ cage: Assembly, guest binding, and stimulus-induced switching. Angewandte Chemie International Edition, 59, 11101-11107. doi: 10.1002/anie.202003220

Journal - Research Other

Lewis, J. E. M., & Crowley, J. D. (2020). Metallo-supramolecular self-assembly with reduced symmetry ligands. ChemPlusChem, 85, 815-827. doi: 10.1002/cplu.202000153

2019

Journal - Research Article

Barnsley, J. E., Findlay, J. A., Shillito, G. E., Pelet, W. S., Scottwell, S. Ø., McIntyre, S. M., Tay, E. J., Gordon, K. C., & Crowley, J. D. (2019). Long-lived MLCT states for Ru(_II) complexes of ferrocene-appended 2,2'-bipyridines. Dalton Transactions, 48, 15713-15722. doi: 10.1039/c9dt02025j

Preston, D., Inglis, A. R., Crowley, J. D., & Kruger, P. E. (2019). Self-assembly and cycling of a three-state Pd_xL_y metallosupramolecular system. Chemistry: An Asian Journal, 14, 3404-3408. doi: 10.1002/asia.201901238

Mapley, J. I., Ross, D. A. W., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2019). Triphenylamine-substituted 2-pyridyl-1,2,3-triazole copper(I) complexes: An experimental and computational investigation. Journal of Coordination Chemistry, 72(8), 1378-1394. doi: 10.1080/00958972.2019.1593388

van Hilst, Q. V. C., Vasdev, R. A. S., Preston, D., Findlay, J. A., Scottwell, S. Ø., Giles, G. I., Brooks, H. J. L., & Crowley, J. D. (2019). Synthesis, characterisation and antimicrobial studies of some 2,6-bis(1,2,3-triazol-4-yl)pyridine ruthenium(II) “click” complexes. Asian Journal of Organic Chemistry, 8, 496-505. doi: 10.1002/ajoc.201900088

Preston, D., Findlay, J. A., & Crowley, J. D. (2019). Recognition properties and self-assembly of planar [M(2-pyridyl-1,2,3-triazole)₂]²⁺ metallo-ligands. Chemistry: An Asian Journal, 14, 1136-1142. doi: 10.1002/asia.201801132

Journal - Research Other

Vasdev, R. A. S., Findlay, J. A., Garden, A. L., & Crowley, J. D. (2019). Redox active [Pd₂L₄]⁴⁺ cages constructed from rotationally flexible 1,1'-disubstituted ferrocene ligands. Chemical Communications, 55, 7506-7509. doi: 10.1039/c9cc03321a

Casini, A., & Crowley, J. D. (2019). Supramolecular metal-based entities for biomedical and biological applications. Frontiers in Chemistry, 7, 293. doi: 10.3389/fchem.2019.00293

Conference Contribution - Verbal presentation and other Conference outputs

Crowley, J. (2019, February). Metallosupramolecular cages: Self-assembly, molecular recognition and catalysis. Invited presentation at the 9th International Conference on Advanced Materials and Nanotechnology (AMN9), Wellington, New Zealand.

Other Research Output

Crowley, J. (2019, August). Molecular scale construction. University of Otago, Dunedin, New Zealand. [Inaugural Professorial Lecture].

2018

Journal - Research Article

Vasdev, R. A. S., Gaudin, L. F., Preston, D., Jogy, J. P., Giles, G. I., & Crowley, J. D. (2018). Anticancer activity and cisplatin binding ability of bis-quinoline and bis-isoquinoline derived Pd₂L₄⁴⁺ metallosupramolecular cages. Frontiers in Chemistry, 6, 563. doi: 10.3389/fchem.2018.00563

Findlay, J. A., Barnsley, J. E., Gordon, K. C., & Crowley, J. D. (2018). Synthesis and light-induced actuation of photo-labile 2-pyridyl-1,2,3-triazole Ru(bis-bipyridyl) appended rerrocene rotors. Molecules, 23(8), 2037. doi: 10.3390/molecules23082037

Preston, D., Gordon, K. C., Sutton, J. J., & Crowley, J. D. (2018). A nona-nuclear heterometallic Pd3Pt6 "Donut" shaped cage: Molecular recognition and photocatalysis. Angewandte Chemie International Edition, 57(28), 8659-8663. doi: 10.1002/anie.201804745

Shillito, G. E., Hall, T. B. J., Preston, D., Traber, P., Wu, L., Reynolds, K. E. A., … Lucas, N. T., Crowley, J. D., … Gordon, K. C. (2018). Dramatic alteration of ³ILCT lifetimes using ancillary ligands in [Re(L)(CO)₃(phen-TPA)]ⁿ⁺ complexes: An integrated spectroscopic and theoretical study. Journal of the American Chemical Society, 140(13), 4534-4542. doi: 10.1021/jacs.7b12868

Findlay, J. A., McAdam, C. J., Sutton, J. J., Preston, D., Gordon, K. C., & Crowley, J. D. (2018). Metallosupramolecular architectures formed with ferrocene-linked bis-bidentate ligands: Synthesis, structures, and electrochemical studies. Inorganic Chemistry, 57(7), 3602-3614. doi: 10.1021/acs.inorgchem.7b02503

van Hilst, Q. V. C., Lagesse, N. R., Preston, D., & Crowley, J. D. (2018). Functional metal complexes from CuAAC "click" bidentate and tridentate pyridyl-1,2,3-triazole ligands. Dalton Transactions, 4, 997-1002. doi: 10.1039/c7dt04570k

Journal - Research Other

Kim, T. Y., Vasdev, R. A. S., Preston, D., & Crowley, J. D. (2018). Strategies for reversible guest uptake and release from metallosupramolecular architectures. Chemistry: A European Journal, 24(56), 14878-14890. doi: 10.1002/chem.201802081

Findlay, J. A., & Crowley, J. D. (2018). Functional Nanomachines: Recent advances in synthetic molecular machinery. Tetrahedron Letters, 59(4), 334-346. doi: 10.1016/j.tetlet.2017.12.036

2017

Journal - Research Article

Ross, D. A. W., Preston, D., & Crowley, J. D. (2017). Self-Assembly with 2,6-Bis(1-(pyridin-4-ylmethyl)-1H-1,2,3-triazol-4-yl)pyridine: Silver(I) and Iron(II) Complexes. Molecules, 22(10), 1762. doi: 10.3390/molecules22101762

Kim, T. Y., Digal, L., Gardiner, M. G., Lucas, N. T., & Crowley, J. D. (2017). Octahedral [Pd₆L₈]¹²⁺ metallosupramolecular cages: Synthesis, structures and guest-encapsulation studies. Chemistry: A European Journal, 23, 15089-15097. doi: 10.1002/chem.201702518

Vasdev, R. A. S., Preston, D., & Crowley, J. D. (2017). Multicavity metallosupramolecular architectures. Chemistry: An Asian Journal, 12(19), 2513-2523. doi: 10.1002/asia.201700948

Scottwell, S. Ø., Barnsley, J. E., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2017). A ferrocene based switchable molecular folding ruler. Chemical Communications, 53, 7628-7631. doi: 10.1039/C7CC03358C

Preston, D., White, K. F., Lewis, J. E. M., Vasdev, R. A. S., Abrahams, B. F., & Crowley, J. D. (2017). Solid state gas adsorption studies with discrete palladium(II) [Pd₂(L)₄]⁴⁺ cages. Chemistry: A European Journal, 23(44), 10559-10567. doi: 10.1002/chem.201701477

Preston, D., Lewis, J. E. M., & Crowley, J. D. (2017). Multicavity [Pd_nL₄]²ⁿ⁺ cages with controlled segregated binding of different guests. Journal of the American Chemical Society, 139(6), 2379-2386. doi: 10.1021/jacs.6b11982

Vasdev, R. A. S., Preston, D., & Crowley, J. D. (2017). Functional metallosupramolecular architectures using 1,2,3-triazole ligands: It's as easy as 1,2,3 "click". Dalton Transactions, 46(8), 2402-2414. doi: 10.1039/c6dt04702e

Conference Contribution - Published proceedings: Abstract

Wright, J. R., Crowley, J. D., & Lucas, N. T. (2017). Carbon-rich 1,2,3-triazole ligands for Suzuki-Miyaura catalysts. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 84). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Lagesse, N. R., Wright, J. R., Brooks, H. J. L., Zhao, M., & Crowley, J. D. (2017). Cationic gold(I) "click" 1,2,3-triazolylidenes: Synthesis, characterization and in-vitro antibacterial testing. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 70). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Findlay, J. A., & Crowley, J. D. (2017). Metallosupramolecular complexes from ferrocene linked bis-bidentate ligands. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 52). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Kim, T. Y., Crowley, J. D., & Lucas, N. T. (2017). Carbon-rich supramolecular cages. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 49). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

van Hilst, Q., Scottwell, S. Ø., Brooks, H. J. L., & Crowley, J. D. (2017). Synthesis and biological activity of 2,6-Bis(1-alkyl-1,2,3-triazol-4-yl)pyridine Rythenium(II) complexes. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 44). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Barnsley, J. E., Scottwell, S. Ø., Elliott, A. B. S., Gordon, K. C., & Crowley, J. D. (2017). Structural, electronic and computational studies of ferrocene-appended heteroleptic Cu(I) complexes. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 40). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Preston, D., Tucker, R. A. J., Garden, A. L., & Crowley, J. D. (2017). CuAAC "click" ligands in heterometallic supramolecular architectures. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 38). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Vasdev, R. A. S., Casey-Stevens, C. A., Garden, A. L., & Crowley, J. D. (2017). Low symmetry [Pd₂L₄]⁴⁺ cages: Towards micellar drug delivery vectors. Proceedings of the 10th Australasian Organometallics Meeting. (pp. 36). Retrieved from https://www.raci.org.au/divisions/australian-symposium-on-organometallic-chemistry-ozom

Conference Contribution - Verbal presentation and other Conference outputs

Crowley, J., Preston, D., & Lewis, J. E. M. (2017, July). Multicavity [PdnL4]2n+ cages with controlled segregated binding of different guests. Verbal presentation at the International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC) in conjunction with ISACS: Challenges in organic Materials & Supramolecular Chemistry, Cambridge, UK.

2016

Journal - Research Article

Huff, G. S., Lo, W. K. C., Horvath, R., Turner, J. O., Sun, X.-Z., Weal, G. R., Davidson, H. J., Kennedy, A. D. W., McAdam, C. J., Crowley, J. D., … Gordon, K. C. (2016). Excited states of triphenylamine-substituted 2-pyridyl-1,2,3-triazole complexes. Inorganic Chemistry, 55(23), 12238-12253. doi: 10.1021/acs.inorgchem.6b01959

Vasdev, R. A. S., Preston, D., Scottwell, S. Ø., Brooks, H. J. L., Crowley, J. D., & Schramm, M. P. (2016). Oxidatively locked [Co₂L₃]⁶⁺ cylinders derived from bis(bidentate) 2-Pyridyl-1,2,3-triazole "Click" ligands: Synthesis, stability, and antimicrobial studies. Molecules, 21(11), 1548. doi: 10.3390/molecules21111548

Wright, J. R., Crowley, J. D., & Lucas, N. T. (2016). Carbon-rich "click" 1,2,3-triazoles: Hexaphenylbenzene and hexa-peri-hexabenzocoronene-based ligands for Suzuki-Miyaura catalysts. Chemical Communications, 52(88), 12976-12979. doi: 10.1039/c6cc07413h

Kumar, S. V., Scottwell, S. Ø., Waugh, E., McAdam, C. J., Hanton, L. R., Brooks, H. J. L., & Crowley, J. D. (2016). Antimicrobial properties of tris(homoleptic) ruthenium(II) 2-pyridyl-1,2,3-triazole "click" complexes against pathogenic bacteria, including methicillin-resistant Staphylococcus aureus (MRSA). Inorganic Chemistry, 55(19), 9767-9777. doi: 10.1021/acs.inorgchem.6b01574

Preston, D., Barnsley, J. E., Gordon, K. C., & Crowley, J. D. (2016). Controlled formation of heteroleptic [Pd₂(L_a)₂(L_b)₂]⁴⁺ cages. Journal of the American Chemical Society, 138(33), 10578-10585. doi: 10.1021/jacs.6b05629

Barnsley, J. E., Scottwell, S. Ø., Elliott, A. B. S., Gordon, K. C., & Crowley, J. D. (2016). Structural, electronic, and computational studies of heteroleptic Cu(I) complexes of 6,6′-dimesityl-2,2′-bipyridine with ferrocene-appended ethynyl-2,2′-bipyridine ligands. Inorganic Chemistry, 55(16), 8184-8192. doi: 10.1021/acs.inorgchem.6b01300

Preston, D., Tucker, R. A. J., Garden, A. L., & Crowley, J. D. (2016). Heterometallic [M_nPt_n(L)_2n]^x+ macrocycles from dichloromethane-derived bis-2-pyridyl-1,2,3-triazole ligands. Inorganic Chemistry, 55(17), 8928-8934. doi: 10.1021/acs.inorgchem.6b01435

Pages, B. J., Sakoff, J., Gilbert, J., Zhang, Y., Li, F., Preston, D., Crowley, J. D., & Aldrich-Wright, J. R. (2016). Investigating the cytotoxicity of platinum(II) complexes incorporating bidentate pyridyl-1,2,3-triazole “click” ligands. Journal of Inorganic Biochemistry, 165, 92-99. doi: 10.1016/j.jinorgbio.2016.06.017

Preston, D., McNeill, S. M., Lewis, J. E. M., Giles, G. I., & Crowley, J. D. (2016). Enhanced kinetic stability of [Pd₂L₄]⁴⁺ cages through ligand substitution. Dalton Transactions, 45, 8050-8060. doi: 10.1039/c6dt00133e

Lo, W. K. C., Castillo, C. E., Gueret, R., Fortage, J., Rebarz, M., Sliwa, M., … McAdam, C. J., … McMorran, D. A., Crowley, J. D., … Blackman, A. G. (2016). Synthesis, characterization, and photocatalytic H₂-evolving activity of a family of [Co(N4Py)(X)]ⁿ⁺ complexes in aqueous solution. Inorganic Chemistry, 55, 4564-4581. doi: 10.1021/acs.inorgchem.6b00391

Elliott, A. B. S., Lewis, J. E. M., van der Salm, H., McAdam, C. J., Crowley, J. D., & Gordon, K. C. (2016). Luminescent cages: Pendant emissive units on [Pd₂L₄]⁴⁺ "click" cages. Inorganic Chemistry, 55(7), 3440-3447. doi: 10.1021/acs.inorgchem.5b02843

McKay, A. P., Lo, W. K. C., Preston, D., Giles, G. I., Crowley, J. D., Barnsley, J. E., Gordon, K. C., & McMorran, D. A. (2016). Palladium(II) and platinum(II) complexes of ((2-pyridyl)pyrazol-1-ylmethyl)benzoic acids: Synthesis, solid state characterisation and biological cytotoxicity. Inorganica Chimica Acta, 446, 41-53. doi: 10.1016/j.ica.2016.02.038

Scottwell, S. Ø., & Crowley, J. D. (2016). Ferrocene-containing non-interlocked molecular machines. Chemical Communications, 52, 2451-2464. doi: 10.1039/c5cc09569g

Conference Contribution - Published proceedings: Abstract

McNeill, S. M., Hewitt, E. F., Preston, D., Crowley, J. D., & Giles, G. (2016). Cytotoxic mechanism of supramolecular helicates. Free Radical Biology & Medicine, 100(Suppl.), (pp. S23-S24). doi: 10.1016/j.freeradbiomed.2016.10.056

Crowley, J. D., Vellas, S. K., Hanton, L. R., & Brooks, H. J. L. (2016). Antimicrobial properties of mono- and di-metallic 2-pyridyl-1,2,3-triazole “click” complexes. Proceedings of the Diagnostics, Drugs, Devices, Discovery (D4) Conference. Retrieved from http://www.otago.ac.nz/d4/index.html

van Hilst, Q., Scottwell, S. Ø., Brooks, H. J. L., & Crowley, J. D. (2016). Synthesis and study of biologically active 2,6-bis(1-alkyl-1H-1,2,3-triazol-4-yl)pyridine ruthenium(II) complexes. Proceedings of the Diagnostics, Drugs, Devices, Discovery (D4) Conference. Retrieved from http://www.otago.ac.nz/d4/index.html

Preston, D., McNeill, S. M., Lewis, J. E. M., Giles, G. I., & Crowley, J. D. (2016). Assessing the biological stability of metallosupramolecular architectures. Proceedings of the Diagnostics, Drugs, Devices, Discovery (D4) Conference. Retrieved from http://www.otago.ac.nz/d4/index.html

Vasdev, R. A. S., Preston, D., Scottwell, S. Ø., Schramm, M. P., Brooks, H. J. L., & Crowley, J. D. (2016). Oxidatively locked [Co₂L₃]⁶⁺ cylinders derived from bis(bidentate) 2-pyridyl-1,2,3-triazole “click” ligands: Synthesis, stability and antibacterial studies. Proceedings of the Diagnostics, Drugs, Devices, Discovery (D4) Conference. Retrieved from http://www.otago.ac.nz/d4/index.html

Findlay, J. A., Scottwell, S. Ø., & Crowley, J. D. (2016). Electrochemical extension and contraction of ferrocene based molecular folding rulers. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Retrieved from http://www.nzic16.org/

Vasdev, R. A. S., Preston, D., Scottwell, S. Ø., Schramm, M. P., Giles, G. I., Brooks, H. J. L., & Crowley, J. D. (2016). Oxidatively locked [Co₂L₃]⁶⁺ cylinders derived from bis(bidentate) 2-pyridyl-1,2,3-triazole "click" ligands: Synthesis, stability and cytotoxicity. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Retrieved from http://www.nzic16.org/

Preston, D., Lewis, J. E. M., Barnsley, J. E., Gordon, K. C., & Crowley, J. D. (2016). Induced structural changes in Palladium(II) cages. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Retrieved from http://www.nzic16.org/

2015

Journal - Research Article

Kim, T. Y., Lucas, N. T., & Crowley, J. D. (2015). A diaryl-linked [Pd₂L₄]⁴⁺ metallosupramolecular architecture: Synthesis, structures and cisplatin binding studies. Supramolecular Chemistry, 27(11-12), 734-745. doi: 10.1080/10610278.2015.1063633

Cubanski, J. R., Reish, M. E., Blackman, A. G., Steel, P. J., Gordon, K. C., McMorran, D. A., & Crowley, J. D. (2015). Hybrid pyrazolyl-1,2,3-triazolyl tripodal tetraamine ligands: Click synthesis and cobalt(III) complexes. Australian Journal of Chemistry, 68(7), 1160-1170. doi: 10.1071/CH14700

Lo, W. K. C., Huff, G. S., Preston, D., McMorran, D. A., Giles, G. I., Gordon, K. C., & Crowley, J. D. (2015). A dinuclear platinum(II) N4Py complex: An unexpected coordination mode for N4Py. Inorganic Chemistry, 54(14), 6671-6673. doi: 10.1021/acs.inorgchem.5b01032

McNeill, S. M., Preston, D., Lewis, J. E. M., Robert, A., Knerr-Rupp, K., Graham, D. O., Wright, J. R., Giles, G. I., & Crowley, J. D. (2015). Biologically active [Pd₂L₄]⁴⁺ quadruply-stranded helicates: Stability and cytotoxicity. Dalton Transactions, 44, 11129-11136. doi: 10.1039/c5dt01259g

Preston, D., Fox-Charles, A., Lo, W. K. C., & Crowley, J. D. (2015). Chloride triggered reversible switching from a metallosupramolecular [Pd₂L₄]⁴⁺ cage to a [Pd₂L₂Cl₄] metallo-macrocycle with release of endo- and exo-hedrally bound guests. Chemical Communications, 51, 9042-9045. doi: 10.1039/C5CC02226F

Scottwell, S. Ø., Elliott, A. B. S., Shaffer, K. J., Nafady, A., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2015). Chemically and electrochemically induced expansion and contraction of a ferrocene rotor. Chemical Communications, 51, 8164. doi: 10.1039/c5cc01973g

Lo, W. K. C., Huff, G. S., Cubanski, J. R., Kennedy, A. D. W., McAdam, C. J., McMorran, D. A., Gordon, K. C., & Crowley, J. D. (2015). Comparison of inverse and regular 2-pyridyl-1,2,3-triazole "click" complexes: Structures, stability, electrochemical, and photophysical properties. Inorganic Chemistry, 54(4), 1572-1587. doi: 10.1021/ic502557w

Lo, W. K. C., McAdam, C. J., Blackman, A. G., Crowley, J. D., & McMorran, D. A. (2015). The pentadentate ligands 2PyN2Q and N4Py, and their Cu(II) and Zn(II) complexes: A synthetic, spectroscopic and crystallographic structural study. Inorganica Chimica Acta, 426, 183-194. doi: 10.1016/j.ica.2014.11.036

Kumar, S. V., Lo, W. K. C., Brooks, H. J. L., & Crowley, J. D. (2015). Synthesis, structure, stability and antimicrobial activity of a ruthenium(II) helicate derived from a bis-bidentate "click" pyridyl-1,2,3-triazole ligand. Inorganica Chimica Acta, 425, 1-6. doi: 10.1016/j.ica.2014.10.011

Noor, A., Maloney, D. L., Lewis, J. E. M., Lo, W. K. C., & Crowley, J. D. (2015). Acid–base driven ligand exchange with palladium(II) "click" complexes. Asian Journal of Organic Chemistry, 4(3), 208-211. doi: 10.1002/ajoc.201402197

Conference Contribution - Poster Presentation (not in published proceedings)

Kim, T. Y., Crowley, J. D., & Lucas, N. T. (2015, February). Synthesis of carbon-rich supramolecular cages. Poster session presented at the Seventh International Conference on Advanced Materials & Nanotechnology (AMN-7), Nelson, New Zealand.

Conference Contribution - Verbal presentation and other Conference outputs

Scottwell, S. Ø., Shaffer, K. J., Elliott, A. B. S., Gordon, K. C., & Crowley, J. D. (2015, February). Reversible contraction and expansion of a ferrocene-based molecular actuator. Verbal presentation at the Seventh International Conference on Advanced Materials & Nanotechnology (AMN-7), Nelson, New Zealand.

Noor, A., Moratti, S. C., & Crowley, J. D. (2015, February). "Click" [2]rotaxane ligands: Building blocks for metallo-supramolecular polyrotaxanes. Verbal presentation at the Seventh International Conference on Advanced Materials & Nanotechnology (AMN-7), Nelson, New Zealand.

2014

Journal - Research Article

Noor, A., Moratti, S. C., & Crowley, J. D. (2014). Active-template synthesis of "click" [2]rotaxane ligands: Self-assembly of mechanically interlocked metallo-supramolecular dimers, macrocycles and oligomers. Chemical Science, 5(11), 4283-4290. doi: 10.1039/c4sc01438c

Noor, A., Huff, G. S., Kumar, S. V., Lewis, J. E. M., Paterson, B. M., Schieber, C., … Brooks, H. J. L., Gordon, K. C., Moratti, S. C., & Crowley, J. D. (2014). [Re(CO)₃]⁺ complexes of exo-functionalized tridentate "click" macrocycles: Synthesis, stability, photophysical properties, bioconjugation, and antibacterial activity. Organometallics, 33(24), 7031-7043. doi: 10.1021/om500664v

Scott, S. Ø., Shaffer, K. J., McAdam, C. J., & Crowley, J. D. (2014). 5-Ferrocenyl-2,2′-bipyridine ligands: Synthesis, palladium(II) and copper(I) complexes, optical and electrochemical properties. RSC Advances, 4(67), 35726-35734. doi: 10.1039/c4ra05333h

Noor, A., Lo, W. K. C., Moratti, S. C., & Crowley, J. D. (2014). CuAAC "click" active-template synthesis of functionalised [2]rotaxanes using small exo-substituted macrocycles: How small is too small? Chemical Communications, 50, 7044-7047. doi: 10.1039/c4cc03077j

Lewis, J. E. M., Elliott, A. B. S., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2014). 'Click' to functionalise: Synthesis, characterisation and enhancement of the physical properties of a series of exo- and endo-functionalised Pd₂L₄ nanocages. Chemical Science, 5, 1833-1843. doi: 10.1039/C4SC00434E

Lewis, J. E. M., & Crowley, J. D. (2014). Exo- and endo-hedral interactions of counteranions with tetracationic Pd₂L₄ metallosupramolecular architectures. Supramolecular Chemistry, 26(3-4), 173-181.

Lo, W. K. C., Cavigliasso, G., Stranger, R., Crowley, J. D., & Blackman, A. G. (2014). Five-coordinate [Pt^II(bipyridine)₂(phosphine)]^π+ complexes: Long-lived intermediates in ligand substitution reactions of [Pt(bipyridine)₂]²⁺ with phosphine ligands. Inorganic Chemistry, 53(7), 3595-3605. doi: 10.1021/ic403089j

Conference Contribution - Poster Presentation (not in published proceedings)

Lo, W. K. C., Cavigliasso, G., Stranger, R., Crowley, J. D., & Blackman, A. G. (2014, July). Formation of a five-coordinate [PtII(bpy)2(L)]n+ intermediate: The first step in overcoming the chelate effect. Poster session presented at the 41st International Conference on Coordination Chemistry (ICCC), Singapore.

2013

Journal - Research Article

Wright, J. R., Young, P. C., Lucas, N. T., Lee, A.-L., & Crowley, J. D. (2013). Gold(I) and Palladium(II) complexes of 1,3,4-trisubstituted 1,2,3-triazol-5-ylidene "click" carbenes: Systematic study of the electronic and steric influence on catalytic activity. Organometallics, 32(23), 7065-7076. doi: 10.1021/om400773n

Lewis, J. E. M., & Crowley, J. D. (2013). Copper(II) complexes of a tripyridyl ligand: Anion-dependent metallosupramolecular structures. Australian Journal of Chemistry, 66(11), 1447-1454. doi: 10.1071/CH13379

Vellas, S. K., Lewis, J. E. M., Shankar, M., Sagatova, A., Tyndall, J. D. A., Monk, B. C., Fitchett, C. M., Hanton, L. R., & Crowley, J. D. (2013). [Fe₂L₃]⁴⁺ cylinders derived from bis(bidentate) 2-pyridyl-1,2,3-triazole "click" ligands: Synthesis, structures and exploration of biological activity. Molecules, 18(6), 6383-6407. doi: 10.3390/molecules18066383

Cavigliasso, G., Stranger, R., Lo, W. K. C., Crowley, J. D., & Blackman, A. G. (2013). The nature of species derived from [Pt(bipy)₂]²⁺ in aqueous solution: X-ray structural, mass spectral, NMR, and computational studies. Polyhedron, 64, 238-246. doi: 10.1016/j.poly.2013.05.004

Lewis, J. E. M., McAdam, C. J., Gardiner, M. G., & Crowley, J. D. (2013). A facile "click" approach to functionalised metallosupramolecular architectures. Chemical Communications, 33, 3398-3400. doi: 10.1039/c3cc41209a

Anderson, C. B., Elliott, A. B. S., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2013). fac-Re(CO)₃Cl complexes of [2-(4-R-1H-1,2,3-Triazol-1-yl) methyl]pyridine inverse "click" ligands: A systematic synthetic, spectroscopic, and computational study. Organometallics, 32(3), 788-797. doi: 10.1021/om300868k

Cubanski, J. R., Cameron, S. A., Crowley, J. D., & Blackman, A. G. (2013). Low symmetry pyrazole-based tripodal tetraamine ligands: Metal complexes and ligand decomposition reactions. Dalton Transactions, 42(6), 2174-2185. doi: 10.1039/C2DT32200E

Kim, T. Y., Elliott, A. B. S., Shaffer, K. J., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2013). Rhenium(I) complexes of readily functionalized bidentate pyridyl-1,2,3-triazole “click” ligands: A systematic synthetic, spectroscopic and computational study. Polyhedron, 52, 1391-1398. doi: 10.1016/j.poly.2012.05.003

Conference Contribution - Published proceedings: Abstract

Cubanski, J., McMorran, D., Blackman, A., & Crowley, J. (2013). Towards multimetallic architectures incorporating 1,2,3-triazole donors. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Christchurch, New Zealand: NZIC. [Abstract]

Lewis, J. E. M., Elliott, A. B. S., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2013). CuAAC 'Click'-functionalised metallosupramolecular architectures as cisplatin drug delivery vectors. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Christchurch, New Zealand: NZIC. [Abstract]

Crowley, J. D. (2013). Functional supramolecular metal complexes: Just a "click" away. Proceedings of the New Zealand Institute of Chemistry (NZIC) Conference. Christchurch, New Zealand: NZIC. [Abstract]

Elliott, A. B. S., Kim, T. Y., Shaffer, K. J., McAdam, C. J., Crowley, J. D., & Gordon, K. C. (2013). Spectroscopic and computational studies of a family of bidentate pyridyl-1,2,3-triazole rhenium (I) complexes. Proceedings of the Sixth International Conference on Advanced Materials and Nanotechnology (AMN6). [USB Memory Stick] [Abstract]

Conference Contribution - Poster Presentation (not in published proceedings)

McNeill, S. M., Robert, A., Knerr, K., Lewis, J., Crowley, J. D., & Giles, G. I. (2013, August). The potential use of palladium metallosupramolecular cages as drug targeting agents for cancer therapy. Poster session presented at the Queenstown Molecular Biology (QMB) Meetings, Queenstown, New Zealand.

Conference Contribution - Verbal presentation and other Conference outputs

Crowley, J. (2013, July). Tooling up for the nanoworld: Developing synthetic molecular machines. Plenary presentation at the ChemEd Conference, Dunedin, New Zealand.

2012

Chapter in Book - Research

Crowley, J. D., & McMorran, D. A. (2012). "Click triazole" Coordination chemistry: Exploiting 1,4-disubstituted-1,2,3-triazoles as ligands. In J. Košmrlj (Ed.), Click triazoles: Topics in heterocyclic chemistry (Vol. 28). (pp. 31-83). Berlin, Germany: Springer. doi: 10.1007/7081_2011_67

Journal - Research Article

Anderson, C. B., Elliott, A. B. S., Lewis, J. E. M., McAdam, C. J., Gordon, K. C., & Crowley, J. D. (2012). fac-Re(CO)₃ complexes of 2,6-bis(4-substituted-1,2,3-triazol-1-ylmethyl)-pyridine "click" ligands: Synthesis, characterisation and photophysical properties. Dalton Transactions, 48, 14625-14632. doi: 10.1039/c2dt31569f

Noor, A., Lewis, J. E. M., Cameron, S. A., Moratti, S. C., & Crowley, J. D. (2012). A multi-component CuAAC 'click' approach to an exo functionalised pyridyl-1,2,3-triazole macrocycle: Synthesis, characterisation, Cu(I) and Ag(I) complexes. Supramolecular Chemistry, 24(7), 492-498. doi: 10.1080/10610278.2012.688126

Wright, J. R., Shaffer, K. J., McAdam, C. J., & Crowley, J. D. (2012). 3,5-Diferrocenylpyridine: Synthesis, characterisation, palladium(II) dichloride complex and electrochemistry. Polyhedron, 36(1), 73-78. doi: 10.1016/j.poly.2012.01.028

Lewis, J. E. M., Gavey, E. L., Cameron, S. A., & Crowley, J. D. (2012). Stimuli-responsive Pd₂L₄ metallosupramolecular cages: Towards targeted cisplatin drug delivery. Chemical Science, 3, 778-784. doi: 10.1039/c2sc00899h

Conference Contribution - Poster Presentation (not in published proceedings)

Lewis, J., Cameron, S., & Crowley, J. (2012, September). M₂L₄ metallosupramolecular nanocages as potential cisplatin drug delivery vectors. Poster session presented at the 40th International Conference on Coordination Chemistry (ICCC), Valencia, Spain.

Lo, W. K. C., Crowley, J., & Blackman, A. (2012, September). Co(III) complexes of a pyridyl-based ligand: Hydrolysis and facile C-H exchange. Poster session presented at the 40th International Conference on Coordination Chemistry (ICCC), Valencia, Spain.

Cubanski, J., Crowley, J., & Blackman, A. (2012, September). Reactivity of tripodal ligands incorporating pyrazolyl moieties. Poster session presented at the 40th International Conference on Coordination Chemistry (ICCC), Valencia, Spain.

Noor, A., Crowley, J., & Moratti, S. (2012, January-February). Click chemistry approaches towards the synthesis of daisy chain click polyrotaxanes. Poster session presented at the 7th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC), Dunedin, New Zealand.

Lewis, J. E. M., Gavey, E. L., & Crowley, J. D. (2012, January-February). Self-assembly, disassembly and reassembly of an M₂L₄ nanocage for drug delivery. Poster session presented at the 7th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC), Dunedin, New Zealand.

Crowley, J. D., Gavey, E. L., Gower, M. L., Scott, S. Ø., Kilpin, K. J., & Bandeen, P. H. (2012, January-February). Functional ligands: It's as easy as 1,2,3"click". Poster session presented at the 7th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC), Dunedin, New Zealand.

Anderson, C. B., & Crowley, J. D. (2012, January-February). Synthesis of Rhenium(I) 'click' complexes towards biotargetted luminescent probes. Poster session presented at the 7th International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC), Dunedin, New Zealand.

2011

Chapter in Book - Research

Crowley, J. D., Kilpin, K. J., & Keep, C. C. (2011). Exploiting ferrocene to develop synthetic molecular machines. In E. S. Phillips (Ed.), Ferrocenes: Compounds, properties and applications. (pp. 149-188). New York: Nova Science.

Journal - Research Article

Crowley, J. D., Lee, A.-L., & Kilpin, K. J. (2011). 1,3,4-trisubstituted-1,2,3-triazol-5-ylidene 'Click' carbene ligands: Synthesis, catalysis and self-assembly. Australian Journal of Chemistry, 64(8), 1118-1132. doi: 10.1071/ch11185

Scott, S. Ø., Gavey, E. L., Lind, S. J., Gordon, K. C., & Crowley, J. D. (2011). Self-assembled palladium(II) “click″ cages: Synthesis, structural modification and stability. Dalton Transactions, 40, 12117-12124. doi: 10.1039/c1dt10551e

Kilpin, K. J., Gavey, E. L., McAdam, C. J., Anderson, C. B., Lind, S. J., Keep, C. C., Gordon, K. C., & Crowley, J. D. (2011). Palladium(II) complexes of readily functionalized bidentate 2-pyridyl-1,2,3-triazole ″Click″ ligands: A synthetic, structural, spectroscopic, and computational study. Inorganic Chemistry, 50, 6334-6346. doi: 10.1021/ic200789b

Kilpin, K. J., Gower, M. L., Telfer, S. G., Jameson, G. B., & Crowley, J. D. (2011). Toward the self-assembly of metal—organic nanotubes using metal—metal and π-stacking interactions: Bis(pyridylethynyl) silver(I) metallo-macrocycles and coordination polymers. Inorganic Chemistry, 50, 1123-1134. doi: 10.1021/ic1020059

Kilpin, K. J., Paul, U. S. D., Lee, A.-L., & Crowley, J. D. (2011). Gold(I) "click" 1,2,3-triazolylidenes: Synthesis, self-assembly and catalysis. Chemical Communications, 47(1), 328-330. doi: 10.1039/c0cc02185g

2010

Journal - Research Article

Kilpin, K. J., Horvath, R., Jameson, G. B., Telfer, S. G., Gordon, K. C., & Crowley, J. D. (2010). Pyridyl gold(I) alkynyls: A synthetic, structural, spectroscopic, and computational study. Organometallics, 29(23), 6186-6195. doi: 10.1021/om1003978

Kilpin, K. J., & Crowley, J. D. (2010). Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3-triazole "click" ligands: Synthesis, properties and X-ray structures. Polyhedron, 29(16), 3111-3117. doi: 10.1016/j.poly.2010.08.021

Crowley, J. D., Goldup, S. M., Gowans, N. D., Leigh, D. A., Ronaldson, V. E., & Slawin, A. M. Z. (2010). An unusual nickel—copper-mediated alkyne homocoupling reaction for the active-template synthesis of [2]rotaxanes. Journal of the American Chemical Society, 132, 6243-6248. doi: 10.1021/ja101121j

Crowley, J. D., Hänni, K. D., Leigh, D. A., & Slawin, A. M. Z. (2010). Diels-Alder active-template synthesis of rotaxanes and metal-ion-switchable molecular shuttles. Journal of the American Chemical Society, 132(14), 5309-5314. doi: 10.1021/ja101029u

Crowley, J. D., & Gavey, E. L. (2010). Use of di-1,4-substituted-1,2,3-triazole "click" ligands to self-assemble dipalladium(II) coordinatively saturated, quadruply stranded helicate cages. Dalton Transactions, 39(17), 4035-4037. doi: 10.1039/c003683h

Crowley, J. D., & Bandeen, P. (2010). A multicomponent CuAAC ″click″ approach to a library of hybrid polydentate 2-pyridyl-1,2,3-triazole ligands: New building blocks for the generation of metallosupramolecular architectures. Dalton Transactions, 39(2), 612-623. doi: 10.1039/b911276f

Gower, M. L., & Crowley, J. D. (2010). Self-assembly of silver(I) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole ″click″ ligands. Dalton Transactions, 39(9), 2371-2378. doi: 10.1039/b923211g

Crowley, J. D., Bandeen, P. H., & Hanton, L. R. (2010). A one pot multi-component CuAAC ″click″ approach to bidentate and tridentate pyridyl-1,2,3-triazole ligands: Synthesis, X-ray structures and copper(II) and silver(I) complexes. Polyhedron, 29(1), 70-83. doi: 10.1016/j.poly.2009.06.010

2009

Journal - Research Article

Crowley, J. D., Bandeen, P. H., & Hanton, L. R. (2009). 1-(3-Bromopropyl)-4-(2-pyridyl)-1H-1,2,3-triazole. Acta Crystallographica Section E, E65, o999-01000. doi: 10.1107/s1600536809012148

Crowley, J. D., Goldup, S. M., Lee, A.-L., Leigh, D. A., & Mcburney, R. T. (2009). Active metal template synthesis of rotaxanes, catenanes and molecular shuttles. Chemical Society Reviews, 38(6), 1530-1541. doi: 10.1039/b804243h

2008

Chapter in Book - Research

Crowley, J. D., Kay, E. R., & Leigh, D. A. (2008). Chemically driven artificial molecular machines. In M. Shahinpoor & H.-J. Schneider (Eds.), Intelligent materials. (pp. 1-47). Cambridge, UK: Royal Society of Chemistry.

Conference Contribution - Published proceedings: Abstract

Aucagne, V., Berná, J., Crowley, J. D., Goldup, S. M., Hänni, K. D., Lee, A.-L., & et al (2008). Active metal-template approaches to rotaxanes. Proceedings of the Inorganic Chemistry Conference. (pp. 225). Christchurch, New Zealand: Department of Chemistry, University of Canterbury. [Abstract]

Conference Contribution - Verbal presentation and other Conference outputs

Crowley, J. D., Leigh, D. A., Lusby, P. J., Mcburney, R. T., Perret-Aebi, L.-E., Petzold, C., … Symes, M. D. (2008, November-December). A protonmotive driven palladium containing molecular shuttle. Verbal presentation at the New Zealand Institute of Chemistry, New Zealand Society for Biochemistry and Molecular Biology and the New Zealand Society of Plant Biologists Combined Conference, Dunedin, New Zealand.

Crowley, J. (2008, April). Functional supramolecular systems: Hydrogen storage and the development of molecular machines. Verbal presentation at the 3rd Korea-New Zealand Material Science Workshop, Dunedin, New Zealand.

2007

Journal - Research Article

Crowley, J. D., Leigh, D. A., Lusby, P. J., Mcburney, R. T., Perret-Aebi, L.-E., Petzold, C., … Symes, M. D. (2007). A switchable palladium-complexed molecular shuttle and its metastable positional isomers. Journal of the American Chemical Society, 129, 15085-15090. doi: 10.1021/ja076570h

Berná, J., Crowley, J. D., Goldup, S. M., Hänni, K. D., Lee, A.-L., & Leigh, D. A. (2007). A catalytic palladium active-metal template pathway to [2]Rotaxanes. Angewandte Chemie International Edition, 46, 5709-5713. doi: 10.1002/anie.200701678

Aucagne, V., Berná, J., Crowley, J. D., Goldup, S. M., Hänni, K. D., Leigh, D. A., … Walker, D. B. (2007). Catalytic ″active-metal″ template synthesis of [2]Rotaxanes, [3]Rotaxanes, and molecular shuttles, and some observations on the mechanism of the Cu(I)-catalyzed azide-alkyne 1,3-cycloaddition. Journal of the American Chemical Society, 129, 11950-11963. doi: 10.1021/ja073513f

Crowley, J. D., Hänni, K. D., Lee, A.-L., & Leigh, D. A. (2007). [2]Rotaxanes through palladium active-template oxidative Heck cross-couplings. Journal of the American Chemical Society, 129(40), 12092-12093. doi: 10.1021/ja075219t

Conference Contribution - Poster Presentation (not in published proceedings)

Aucagne, V., Berná, J., Crowley, J. D., Goldup, S. M., Hänni, K. D., Lee, A.-L., … Walker, D. B. (2007, March). Active metal-template approaches to rotaxanes. Poster session presented at the Supramolecular Chemistry and Nanoscience Conference, Dunedin, New Zealand.

Conference Contribution - Verbal presentation and other Conference outputs

Aucagne, V., Berná, J., Crowley, J. D., Goldup, S. M., Hänni, K. D., Lee, A.-L., … Walker, D. B. (2007, March). Active metal-template approaches to rotaxanes. Verbal presentation at the Supramolecular Chemistry and Nanoscience Conference, Dunedin, New Zealand.

2006

Journal - Research Article

Crowley, J. D., Steele, I. M., & Bosnich, B. (2006). Protonmotive force: Development of electrostatic drivers for synthetic molecular motors. Chemistry: A European Journal, 12(35), 8935-8951. doi: 10.1002/chem.200500519